Metal contamination of agricultural soils in the copper mining areas of Singhbhum shear zone in India

The study was intended to investigate the heavy metal contamination in the agricultural soils of the copper mining areas in Singhbhum shear zone, India. The total concentrations of the metals were determined by inductively coupled plasma-mass spectrometer (ICPMS). Pollution levels were assessed by calculating enrichment factor (EF), geo-accumulation index (\(I_\mathrm{geo}\)), contamination factors (CF), pollution load index (PLI), Nemerow index and ecological risk index (\(R_{I}\)). The metal concentrations in the soil samples exceeded the average shale values for almost all the metals. Principal component analysis resulted in extraction of three factors explaining 82.6% of the data variability and indicated anthropogenic contribution of Cu, Ni, Co, Cr, Mn and Pb. The EF and \(I_\mathrm{geo}\) values indicated very high contamination with respect to Cu followed by As and Zn in the agricultural soils. The values of PLI, \(R_{I}\) and Nemerow index, which considered the overall effect of all the studied metals on the soils, revealed that 50% of the locations were highly polluted with respect to metals. The pollution levels varied with the proximity to the copper mining and processing units. Consequently, the results advocate the necessity of periodic monitoring of the agricultural soils of the area and development of proper management strategies to reduce the metal pollution.     

Decolorization of Congo red mediated by marine <Emphasis Type="Italic">Alcaligenes</Emphasis> species isolated from Indian West coast sediments

Alcaligenes species capable of degrading highly recalcitrant, carcinogenic, water-soluble dye—Congo red—were isolated from Indian West coastal sediments. Individual strains showed decolorization rates ranging from 76.49 to 98.76% within 24–48 h. Decolorization was most efficient at anoxic conditions catalyzed by intracellular azoreductase enzyme with an activity of 0.032 µmol min^?1 mg^?1 of protein. Degradation was confirmed by HPLC and FTIR analysis. LC/MS analysis of degraded metabolites established the cleavage of the azo bond-producing biphenyl diamine and 1,2′-diaminonapthalene-4-sulfonic acid. These results signify the effectiveness and ease to engineer processes such as feed batch/immobilized cell systems using these strains as biocatalysts to address the problem of global coastal water pollution caused by increased disposal of azo dye-containing industrial effluents.     

THE OPTIMUM GATE LENGTH FOR THE TIME-VARYING DECONVOLUTION OPERATOR1

The time-varying deconvolution operator designed by dividing time-varying sequence has been extended to include an optimal division of the input data. A numerical example illustrates that the error energy is less in the case of optimally divided input in comparison with arbitrary division.     

IDEAL PERFORMANCE CRITERIA FOR DECONVOLUTION OPERATORS*

A technique to evaluate an ideal performance of a deconvolution operator has been obtained by dividing the input trace into a number of sections. The error energy is seen to decrease with an increase in the number of sections. Numerical examples show that the error energy becomes zero following a relation between the number of sections, the length of input and the length of the filter.     

Heat islands over Mumbai as revealed by autorecorded thermograph data

This study examined hourly temperature data of two locations of Mumbai metropolitan city. One data point (Coloba, Mumbai) is in centre of the city and the other one (Santacruz, Mumbai) is at the airport. The study finds that there were many occasions when night-time hourly temperatures over the city centre were considerably higher than that of the airport, even though temperature at the time of sunset at both the places was nearly same. In this study, the occasions, when hourly night-time temperature over city was more than that of the airport by objectively defined threshold value (3.0 ^°C in this study) for most of the hours in the night, were termed as heat island events. Analysis of the study reveals that these events are mostly confined to November–February months. The study also found that frequency of such events has doubled in recent two decades in comparison to the earlier two decades.     

Lightning Nowcasting with an Algorithm of Thunderstorm Tracking Based on Lightning Location Data over the Beijing Area

A thunderstorm tracking algorithm is proposed to nowcast the possibility of lightning activity over an area of concern by using the total lightning data and neighborhood technique.The lightning radiation sources observed from the Beijing Lightning Network(BLNET)were used to obtain information about the thunderstorm cells,which are significantly valuable in real-time.The boundaries of thunderstorm cells were obtained through the neighborhood technique.After smoothing,these boundaries were used to track the movement of thunderstorms and then extrapolated to nowcast the lightning approaching in an area of concern.The algorithm can deliver creditable results prior to a thunderstorm arriving at the area of concern,with accuracies of 63%,80%,and 91%for lead times of 30,15,and 5 minutes,respectively.The real-time observations of total lightning appear to be significant for thunderstorm tracking and lightning nowcasting,as total lightning tracking could help to fill the observational gaps in radar reflectivity due to the attenuation by hills or other obstacles.The lightning data used in the algorithm performs well in tracking the active thunderstorm cells associated with lightning activities.     

Microtexture and Distribution of Minerals in Hydrothermal Barite-Silica Chimney from the Franklin Seamount, SW Pacific: Constraints on Mode of Formation

An extinct hydrothermal barite-silica chimney from the Franklin Seamount of the Woodlark Basin, in the southwestern Pacific Ocean, was investigated for mineral distribution and geochemical composition. Six layers on either side of the orifice of a chimney show significant disparity in color, mineral assemblage and major element composition. Electron microscope(SEM) images reveal that the peripheral wall of the chimney is composed of colloform silica, suggesting that incipient precipitation of silica-saturated hydrothermal fluid initiated the development of the chimney wall. Intermediate layers, between the exterior wall and the inner fluid-orifice, dominate with barite and sulfides. Low Sr-to-Ba ratios(SrO/BaO = 0.015–0.017) indicate restricted fluid-seawater mixing, which causes relatively high-temperature formation of the intermediate layers. Whereas the innermost layer bordering the chimney orifice is characterized by more silica and a higher Sr-to-Ba ratio(SrO/BaO = 0.023), could have formed due to a paragenetic shift from a high-temperature active phase to a cooler waning stage of formation. A paragenetic shift is also probably responsible for the change in mineral formation mechanism that resulted in the textural variation of barite and colloform silica developed during different growth phases of this barite-silica chimney.     

GPS measurement of land subsidence in Gandhinagar,Gujarat (Western India), due to groundwater depletion

A continuous GPS measurement site, ISRR, at Gandhinagar (Western India), documented ~?5 mm/year of surface subsidence rate during 2009–2016. Preliminary modelling using an analytical solution indicates that the observed surface subsidence rate at the ISRR site is consistent with the ground water depletion reported from Gandhinagar. An assessment of data from GPS sites at Lucknow and Varanasi in the Indo-Gangetic plains in Northern India does not indicate any significant subsidence at these sites which is also consistent with the in situ observations of insignificant depletion of ground water in the region.     

Evolution of the basalts from three back-arc basins of southwest Pacific

Petrography, petrochemistry, and mineral chemistry of basalts from the Woodlark, Manus, and Lau basins from the southwest Pacific, have been studied to understand their magmatic evolution. Basalt from the western Woodlark Basin (Dobu Seamount) indicates mixing of a near-primitive magma with fractionated basaltic melt in shallow magma chambers. Basalts from Manus Basin and Central Lau Spreading Center (Lau Basin) are typical N-MORBs, and they exhibit olivine fractionation under high oxidizing conditions while basalts from Mangatolu Triple Junction (Lau Basin) are enriched in Al₂O₃, K₂O, and Zr indicative of a contribution from a subducting plate.